Some people make the mistake of thinking that if you double a recipe, you must also double the cooking time. That this is an error can be shown by a simple example. Assume it takes 15 minutes to cook a steak in a broiler. If you put two steaks in the broiler, it still takes 15 minutes to cook them, not 30 minutes.
If all other things are equal, cooking times stay the same when a recipe is converted. Problems arise, however, because all other things are not always equal. For example, a large pot of liquid takes longer to bring to a boil than a small pot. Therefore, the total cooking time is longer.