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Published 2006
The free sugar that accumulates in grapes, glucose and fructose, is the result of translocation of sucrose photosynthesized in leaves and moved via phloem tubes into grape berries during ripening, where it is inverted (hydrolysed) by the enzyme invertase. The astonishing feature of grapes is that this accumulation occurs at the same time as water is accumulating in the berry, yet concentration is also increasing; in other words, sugar is increasing proportionately more than water. Other phloem-provided sucrose moves throughout the vine dispensing energy and the carbon skeletons for all organic molecules throughout the vine. Additionally, sugar is used for carbon storage, as starch in wood, and for the formation of glycosides in the storage of secondary metabolites in vacuoles of cells (see flavour precursors and flavour compounds).