Combine pear nectar, cinnamon sticks, cloves, and anise stars in a medium saucepan. Bring to a boil, then reduce heat and simmer for 10 to 15 minutes.
Add tequila and stir to incorporate.
Cut off the pear tops and with a sharp knife carefully outline a rim on your pear cups. With a melon baller or a spoon, hollow out the pears making sure to leave about ¼ inch at the bottom and around the edges, creating a cup.
Pour warm nectar into pear cups and enjoy!
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